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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Carbon–oxygen bond ： ウィキペディア英語版 Carbon–oxygen bond A carbon–oxygen bond is a covalent bond between carbon and oxygen. 〔''Organic Chemistry'' John McMurry 2nd Ed.〕 〔 March, J.; Smith, D. (2001). Advanced Organic Chemistry, 5th ed. New York: Wiley.〕 〔 Advanced Organic Chemistry Carey, Francis A., Sundberg, Richard J. 5th ed. 2007〕 Oxygen has 6 valence electrons and prefers to either share two electrons in bonding with carbon, leaving the 4 nonbonding electrons in 2 lone pairs :Ó: or to share two pairs of electrons to form the carbonyl functional group. =O: Simple representatives of these two bond types are the _OH in alcohols such as the ethanol in beverages and fuels and the C=O in ketones (as well as many other related carbonyl compounds). ==Electronegativities and bond lengths== The C–O bond is strongly polarized towards oxygen (electronegativity of C ''vs'' O, 2.55 ''vs'' 3.44). Bond lengths for paraffinic C–O bonds are in the range of 143 picometer – less than those of C–N or C–C bonds. Shortened single bonds are found with carboxylic acids (136 pm) due to partial double bond character and elongated bonds are found in epoxides (147 pm).〔CRC Handbook of Chemistry and Physics 65Th Ed.〕 The C–O bond strength is also larger than C–N or C–C. For example, bond strengths are 91 kcal/mol (at 298 K) in methanol, 87 kcal/mol in methylamine, and 88 kcal/mol in ethane. 〔 Carbon and oxygen form terminal double bonds in functional groups collectively known as carbonyl compounds to which belong such compounds as ketones, esters, carboxylic acids and many more. Internal C=O bonds are found in positively charged oxonium ions. In furans, the oxygen atom contributes to pi-electron delocalization via its filled p-orbital and hence furans are aromatic. Bond lengths of C=O bonds are around 123 pm in carbonyl compounds. The C=O bonds in acyl halides have partial triple bond character and are subsequently very short: 117 pm. Compounds with formal C–O triple bonds do not exist except for carbon monoxide, which has a very short, strong bond (112.8 pm). Such triple bonds have a very high bond energy, even higher than N–N triple bonds.〔(Standard Bond Energies ), Department of Chemistry, Michigan State University〕 Oxygen can also be trivalent, for example in triethyloxonium tetrafluoroborate. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Carbon–oxygen bond」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.